Conformational Effect of Silica-supported Poly(octadecyl acrylate) on Molecular-Shape Selectivity of Polycyclic Aromatic Hydrocarbons in RP-HPLC

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  • TAKAFUJI Makoto
    Department of Applied Chemistry & Biochemistry, Kumamoto University
  • FUKUI Megumi
    Department of Applied Chemistry & Biochemistry, Kumamoto University
  • ANSARIAN Hamid R.
    SVB Laboratory, Kumamoto University
  • DERAKHSHAN Mahnaz
    Department of Applied Chemistry & Biochemistry, Kumamoto University
  • SHUNDO Atsuomi
    Department of Applied Chemistry & Biochemistry, Kumamoto University
  • IHARA Hirotaka
    Department of Applied Chemistry & Biochemistry, Kumamoto University Institute for Materials Chemistry & Engineering, Kyushu University

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Abstract

Poly(octadecyl acrylate) with a terminal reactive group was synthesized by radical telomerization in various solvents. The polymers were grafted onto porous silica for use in RP-HPLC, and the molecular recognition ability was investigated along with the selectivity for the structural isomers of polycyclic aromatic hydrocarbons. The mechanism of selectivity was also investigated with differential scanning calorimetry and NMR spectroscopic observations.

Journal

  • Analytical Sciences

    Analytical Sciences 20 (12), 1681-1685, 2004

    The Japan Society for Analytical Chemistry

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