Selective Allylation of Arenethiols Using Water-soluble Palladium Complex Catalyst in Recyclable Water/Hexane Biphasic Media

DOI PDF 被引用文献4件 参考文献47件
  • Nobuyuki Komine
    Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology
  • Akari Sako
    Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology
  • Shin-ya Hirahara
    Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology
  • Masafumi Hirano
    Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology
  • Sanshiro Komiya
    Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology

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<jats:title>Abstract</jats:title> <jats:p>Allylation of arenethiols by allylic alcohol with sterically hindered carbon of the allylic moiety is smoothly catalyzed by Pd(OAc)2/TPPTS in biphasic water/hexane media under ambient conditions. The catalyst water layer can be repeatedly reused without catalytic activity loss.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 34 (2), 246-247, 2005-01-22

    Oxford University Press (OUP)

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