Dendritic Nanoreactor Encapsulating Rh Complex Catalyst for Hydroformylation
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- Tomoo Mizugaki
- Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University
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- Yasuaki Miyauchi
- Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University
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- Makoto Murata
- Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University
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- Kohki Ebitani
- Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University
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- Kiyotomi Kaneda
- Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University
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<jats:title>Abstract</jats:title> <jats:p>A Rh phosphine complex was encapsulated within the surface alkylated poly(propylene imine) dendrimers through ionic interactions. The resulting dendrimer complexes functioned as nanoreactors for hydroformylation of olefins. The congested surface of dendrimers with long alkyl chains favored hydroformylation of higher olefins. One-pot three reactions composed of hydroformylation, the Knoevenagel reaction, and hydrogenation proceeded within the dendritic nanoreactor.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 34 (3), 286-287, 2005-01-29
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360283694087355904
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- NII論文ID
- 10014463854
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- NII書誌ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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