Self-organization of Protonated 2-heptadecylimidazole as an Effective Ion Conductive Matrix

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  • MUKAI Tomohiro
    Department of Biotechnology, Tokyo University of Agriculture and Technology
  • YOSHIO Masafumi
    Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo
  • KATO Takashi
    Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo
  • YOSHIZAWA-FUJITA Masahiro
    Department of Biotechnology, Tokyo University of Agriculture and Technology
  • OHNO Hiroyuki
    Department of Biotechnology, Tokyo University of Agriculture and Technology

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<p>2-Heptadecylimidazole (a) neutralized with a series of acids showed good thermal stability. The decomposition temperature of most salts exceeded 200 °C. Among these, a neutralized with HBF4 showed enantiotropic liquid crystalline phase. Higher ionic conductivity and lower activation energy were found for the salt in the liquid crystalline phase. The a neutralized with HBF4 was mixed with 11 mol% a to introduce the proton acceptor sites in the assembled a. The mixture showed a monotropic liquid crystalline phase. High ionic conductivity and low activation energy were also seen in the monotropic liquid crystalline phase.</p>

収録刊行物

  • Electrochemistry

    Electrochemistry 73 (8), 623-626, 2005-08-05

    公益社団法人　電気化学会

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