Transition Metal-catalyzed Direct Borylation and Silylation based on C-H Activation

• Ishiyama Tatsuo

  Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University

Bibliographic Information

Other Title

• 遷移金属触媒を用いたＣ‐Ｈ活性化を機軸とする直接ホウ素化およびケイ素化反応
• 遷移金属触媒を用いたC-H活性化を機軸とする直接ホウ素化およびケイ素化反応
• センイ キンゾク ショクバイ オ モチイタ C H カッセイカ オ キジク ト スル チョクセツ ホウソカ オヨビ ケイソカ ハンノウ

Abstract

Direct borylation and silylation of unreactive C-H bonds catalyzed by transition metal complexes have been extensively studied by several research groups and have become economical, efficient, elegant, and environmentally benign protocols for the synthesis of a variety of organoboron and organosilicon compounds. A number of transition metal complexes catalyzes C-H borylation and silylation of alkanes, arenes, heteroarenes, alkenes, or benzylic positions of alkylarenes by diborons or hydoroboranes and disilanes or hydrosilanes to produce the corresponding alkyl-, aryl-, heteroaryl-, vinyl-, or benzylboron and -silicon compounds, respectively. In this review, seminal early works and exciting recent developments in the area of direct borylation and silylation of hydrocarbons based on C-H activation are summarized.

Journal

• Journal of Synthetic Organic Chemistry, Japan

  Journal of Synthetic Organic Chemistry, Japan 63 (5), 440-452, 2005

  The Society of Synthetic Organic Chemistry, Japan

Keywords

• C-H activation
• transition metal catalyst
• hydrocarbon
• borylation
• silylation
• organoboron compound
• organosilicon compound

Details

• CRID: 1390001205312877312
• NII Article ID: 10015726776
• NII Book ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.63.440
• COI: 1:CAS:528:DC%2BD2MXktlCqtb8%3D
• ISSN: 18836526
• ISSN: 00379980
• ISSN: http://id.crossref.org/issn/00379980
• HANDLE: 2115/14897
• NDL BIB ID: 7362313
• Web Site: http://id.ndl.go.jp/bib/7362313
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I7362313
• Text Lang: ja
• Data Source:
  • JaLC
  • IRDB
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed