Highly Ruffled Manganese(III) Complexes of <i>meso</i>-Tetra(<i>tert</i>-butyl)porphyrin

• Akira Ikezaki

  Department of Chemistry, School of Medicine, Toho University

• Mikio Nakamura

  Department of Chemistry, School of Medicine, Toho University

抄録

Extraordinarily ruffled acetato[5,10,15,20-tetra(tert-butyl)porphinato]manganese(III) has been prepared. The 1H NMR spectra have revealed that the inversion barrier of the porphyrin ring exceeds 66 kJ mol−1 and that the spin densities are quite different between the diastereotopic β-carbon atoms.

収録刊行物

• Chemistry Letters

  Chemistry Letters 34 (7), 1046-1047, 2005-06-18

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360283694087259648
• NII論文ID: 10016469587
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2005.1046
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/34/7/1046/55587232/cl.2005.1046.pdf
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