ヒドロキシメチルフルフラールを原料としたポリエステルの合成

DOI Web Site 被引用文献1件 参考文献6件

書誌事項

タイトル別名
  • Syntheses of Polyesters from 5-Hydroxymethyl-2-Furfural as a Starting Material
  • ヒドロキシメチルフルフラール オ ゲンリョウ ト シタ ポリエステル ノ ゴウセイ

この論文をさがす

抄録

Polyesters were synthesized from 5-hydroxymethyl-2-furfural (HMF), which can be prepared by pyrolysis of biomass or cellulose. 2, 5-Bis (hydroxymethyl) furan (BHF), which was prepared by the reduction of HMF, and natural dicarboxylic acids such as succinic acid, fumaric acid, or maleic acid were polymerized to give polyesters. Polycondensations were carried out by two methods: one used acid chloride and the other one used a condensing reagent. Polycondensation of BHF and succinic acid gave a polymer of which the number averaged degree of polymerization was 30. NMR and IR spectra indicated that the obtained polymers have linear and regular polyesters. Copolymerization performed using the mixture of two kinds of dicarboxylic acids gave the copolymers. DSC measurements of polyesters showed the melting temperature and the grass transition temperature.

収録刊行物

  • 高分子論文集

    高分子論文集 62 (7), 316-320, 2005

    公益社団法人 高分子学会

被引用文献 (1)*注記

もっと見る

参考文献 (6)*注記

もっと見る

関連プロジェクト

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ