Single-component Molecular Conductor [Zn(tmdt)2] and Related Zn Complexes

• Kimiko Yamamoto

  Research Centre for Spectrochemistry, Graduate School of Science, The University of Tokyo

• Emiko Fujiwara

  Research Centre for Spectrochemistry, Graduate School of Science, The University of Tokyo

• Akiko Kobayashi

  Research Centre for Spectrochemistry, Graduate School of Science, The University of Tokyo

• Yuichi Fujishiro

  Department of Applied Physics, Nagoya University

• Eiji Nishibori

  Department of Applied Physics, Nagoya University

• Makoto Sakata

  Department of Applied Physics, Nagoya University

• Masaki Takata

  Japan Synchrotron Radiation Research Institute/SPring-8

• Hisashi Tanaka

  Nanotechnology Research Institute, AIST

• Yoshinori Okano

  Institute for Molecular Science and CREST, JST

• Hayao Kobayashi

  Institute for Molecular Science and CREST, JST

抄録

Single-component molecular conductors based on zinc complexes with filled 3d shells and extended-TTF ligands, [ZnL2] (L = tmdt, dmdt, and dt) were prepared. The crystal structure of semiconducting [Zn(tmdt)2] (ρ (rt) ≈ 50 Ω cm) was determined by the synchrotron radiation X-ray powder diffraction experiments. The molecule has a tetrahedral geometry and two ligand planes are almost perpendicular to each other.

収録刊行物

• Chemistry Letters

  Chemistry Letters 34 (8), 1090-1091, 2005-07-02

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360283694087264512
• NII論文ID: 10016648721
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2005.1090
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/34/8/1090/55585934/cl.2005.1090.pdf
• データソース種別:
  • Crossref
  • CiNii Articles