An Abrupt Spin Crossover FeII Complex Based on Homochiral Chain

• Nicolas Bréfuel

  Department of Chemistry, Faculty of Science, Kumamoto University

• Sergiu Shova

  Institute of Applied Physics, Academy of Sciences of   Moldova

• Jean-Pierre Tuchagues

  Laboratoire de Chimie de Coordination du CNRS, UPR 8241

• Naohide Matsumoto

  Department of Chemistry, Faculty of Science, Kumamoto University

抄録

A new FeII complex with a linear hexadentate ligand involving one terminal imidazole and one terminal imidazolato moiety, [FeHL2-Me]ClO4, has been synthesized, where H2L2-Me denotes [bis(2-methyl-4-formylimidazolidene)aminopropyl]ethylenediamine. This complex shows an abrupt spin-crossover at T1/2 = 165.5 K and assumes a homochiral 1D chain structure through hydrogen bonds between the imidazole and imidazolato groups of adjacent molecules.

収録刊行物

• Chemistry Letters

  Chemistry Letters 34 (8), 1092-1093, 2005-07-02

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219110553856
• NII論文ID: 10016648730
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2005.1092
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/34/8/1092/55585757/cl.2005.1092.pdf
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