Formation of Molecular Wires by Nanospace Polymerization of a Diacetylene Derivative Induced with a Scanning Tunneling Microscope at a Solid-Liquid Interface
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- Nishio Satoru
- Department of Applied Chemistry, Faculty of Science and Engineering, Ritsumeikan University
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- I-i Daizo
- Department of Chemistry, Graduate School of Science, Tohoku University
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- Matsuda Hiroshi
- Department of Chemistry, Graduate School of Science, Tohoku University
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- Yoshidome Masahito
- Department of Chemistry, Graduate School of Science, Tohoku University
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- Uji-i Hiroshi
- Department of Chemistry, Graduate School of Science, Tohoku University
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- Fukumura Hiroshi
- Department of Chemistry, Graduate School of Science, Tohoku University
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Abstract
A nanospace polymerization reaction was initiated using a scanning tunneling microscope in a monolayer of a diacetylene derivative, 10, 12-nonacosadiynoic acid (NCDA), at a solid-liquid interface to obtain molecular wires. The polymerization threshold with respect to the applied voltage was 2 V, which was 1 V lower than that observed at a solid-air interface. The presence of ionic species considerably enhanced the reaction probability. At more than ±2 V, the addition of N(CH3)4ClO4 resulted in the expansion of the reaction region and the increase in reaction probability regardless of the sign of the bias voltage applied. Different from the case at the solid-air interface, polymerization at the solid-liquid interface was probably induced through the multiple vibrational excitation of NCDA by repetitive collisions with charged carriers activated by the strong electric field involved in electron avalanche.
Journal
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- Japanese Journal of Applied Physics
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Japanese Journal of Applied Physics 44 (7B), 5417-5420, 2005
The Japan Society of Applied Physics
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Details 詳細情報について
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- CRID
- 1390001206265752448
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- NII Article ID
- 10016677004
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- NII Book ID
- AA10457675
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- COI
- 1:CAS:528:DC%2BD2MXpsFCmsbs%3D
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- ISSN
- 13474065
- 00214922
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- NDL BIB ID
- 7378380
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed