Structural Aspects of 1,2-Dioxetanes Active toward Intramolecular Charge-Transfer-Induced Chemiluminescent Decomposition

• Matsumoto Masakatsu

  Department of Chemistry, Kanagawa University

• Watanabe Nobuko

  Department of Chemistry, Kanagawa University

Bibliographic Information

Other Title

• Accounts: Structural Aspects of 1,2-Dioxetanes Active toward Intramolecular Charge-Transfer-Induced Chemiluminescent Decomposition

Abstract

Simple 1,2-dioxetanes decompose thermally to produce mainly triplet-excited carbonyl fragments, whereas 1,2-dioxetanes bearing an aromatic electron donor display intramolecular charge-transfer-induced decomposition with accompanying effective emission of light. This type of 1,2-dioxetanes has been extensively studied with a view to understanding the mechanisms of bioluminescence and chemiluminescence and applying them to modern biochemical and biomedical analyses. In this account, recent developments of dioxetane-based chemiluminescent substrates are described from the viewpoint of relationships between the structure of dioxetanes and the properties of chemiluminescence, namely, chemiluminescent efficiency, singlet-chemiexcitation efficiency, color, and the rate of chemiluminescent decomposition.

Journal

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 78 (11), 1899-1920, 2005

  The Chemical Society of Japan

Keywords

• General Chemistry

Details

• CRID: 1390282679104091264
• NII Article ID: 10016844724
• NII Book ID: AA00580132
• DOI: 10.1246/bcsj.78.1899
• ISSN: 13480634
• ISSN: 00092673
• NDL BIB ID: 7695489
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I7695489
• Web Site: https://academic.oup.com/bcsj/article-pdf/78/11/1899/56266641/bcsj.78.1899.pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed