Catalytic Synthesis of α-Hydroxy Ketones Using Organic–Inorganic Hybrid Polymer

• Takayoshi Arai

  Department of Chemistry, Faculty of Science, Chiba University

• Hitomi Takasugi

  Graduate School of Science and Technology, Chiba University

• Toru Sato

  Department of Chemistry, Faculty of Science, Chiba University

• Hiroshi Noguchi

  Graduate School of Science and Technology, Chiba University

• Hirofumi Kanoh

  Department of Chemistry, Faculty of Science, Chiba University

• Katsumi Kaneko

  Department of Chemistry, Faculty of Science, Chiba University

• Akira Yanagisawa

  Department of Chemistry, Faculty of Science, Chiba University

抄録

Oxidation of silyl enolates was found to be smoothly catalyzed by [Cu(bpy)(BF4)2(H2O)2(bpy)]n (bpy = 4,4′-bipyridine) under molecular oxygen, and provided the corresponding α-hydroxy carbonyl compounds in high yield. The insoluble organic–inorganic hybrid polymer was readily recovered by centrifugation after the completion of reaction, and the recovered catalyst could be reused.

収録刊行物

• Chemistry Letters

  Chemistry Letters 34 (12), 1590-1591, 2005-10-27

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219110614912
• NII論文ID: 10016891488
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2005.1590
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/34/12/1590/55586934/cl.2005.1590.pdf
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