Reversible Capture of Electrogenerated Intermediates by Liquefiable Micro-particles Containing an Amphiphilic Tag

• HAYASHI Kanako

  Laboratory of Bio-organic Chemistry, Tokyo University of Agriculture and Technology

• KIM Shokaku

  Laboratory of Bio-organic Chemistry, Tokyo University of Agriculture and Technology

• CHIBA Kazuhiro

  Laboratory of Bio-organic Chemistry, Tokyo University of Agriculture and Technology

Abstract

Liquefiable micelle-like micro-particles possessing maleimide moieties on the surface, which allow reversible capture of electrogenerated iminium cation intermediates of pyrrolidine derivatives, were prepared. It was found that the particles efficiently captured the aimed intermediates, allowing separation from the electrolyte solution, and could be made to release the tagged product simply by thermal liquefaction. The tag introduced to the pyrrolidine was easily removed by electro-oxidative carbon-sulfur bond cleavage under mild condition.

Journal

• Electrochemistry

  Electrochemistry 74 (8), 621-624, 2006

  The Electrochemical Society of Japan

Keywords

• Electrochemical Reaction
• Micelle
• Amphiphilic
• Iminium Cation

Details

• CRID: 1390001206497488512
• NII Article ID: 130002150948
• NII Article ID: 10017390017
• NII Book ID: AN00151637
• DOI: 10.5796/electrochemistry.74.621
• COI: 1:CAS:528:DC%2BD28XosVSntLg%3D
• ISSN: 21862451
• ISSN: 13443542
• NDL BIB ID: 8059634
• Web Site: http://id.ndl.go.jp/bib/8059634
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8059634
• Web Site: https://www.jstage.jst.go.jp/article/electrochemistry/74/8/74_8_621/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Allowed