金属内包フラーレンの構造

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タイトル別名
  • Structures of Endohedral Metallofullerenes
  • サイキン ノ ケンキュウ カラ キンゾク ナイホウ フラーレン ノ コウゾウ

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The structures of many typical endohedral metallofullerenes have been reported by the powder X-ray analysis. For example, the report of the trimetallofullerene Sc3C82has shown that the endohedral structure is Sc3@C82, this being widely accepted. However, the recent13C NMR spectroscopy and X-ray single crystal analysis have revealed that the structure of Sc3C82is not Sc3@C82but Sc3C2@C80. This may suggest that the endohedral structures reported from the powder X-ray study are not always reliable even in a qualitative sense.

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