新規シルセスキオキサンの合成と触媒機能

• 和田 健司

  京都大学大学院工学研究科

• 光藤 武明

  京都大学

書誌事項

タイトル別名

• Preparation and the Activity of Novel Silsesquioxane-Based Catalysts
• シンキ シルセスキオキサン ノ ゴウセイ ト ショクバイ キノウ

抄録

Preparation of novel oligosilsesquioxanes-based materials and metal-containing ones as homogeneous and heterogeneous catalysts of excellent activity are reviewed. The authors examined the activity of a V-containing silsesquioxane as a homogeneous catalyst for the photo-oxidation of simple alkanes. For the epoxidation of alkenes catalyzed by Ti-silsesquioxanes, the presence of alkenylsilyl substituents around the Ti center shows significant promotional effects. By utilizing silsesquioxanes bearing appropriate functional groups, novel caged molecules with organic-inorganic hybrid structures were prepared as well as soluble cooligomers, starburst-type polymers, and a dendrimer containing metallasilsesquioxanes. Furthermore, the authors found that these metal-containing silsesquioxanes can be good precursors of oxide catalysts with high BET surface areas and uniformly-controlled pores. Remarkably, the catalysts containing V and Al species were found to show excellent activity for photo-assisted aerobic oxidation of methane into methanal and the cracking of cumene, respectively.

収録刊行物

• 有機合成化学協会誌

  有機合成化学協会誌 64 (8), 836-844, 2006

  公益社団法人 有機合成化学協会

キーワード

• metal-containing silsesquioxanes
• organic-inorganic hybrid catalysts
• oxidation of alkanes
• epoxidation of alkenes
• porous oxide catalysts
• cracking of hydrocarbons

詳細情報

• CRID: 1390282680289596672
• NII論文ID: 10017652306
• NII書誌ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.64.836
• ISSN: 18836526
• ISSN: 00379980
• NDL書誌ID: 8060097
• Web Site: http://id.ndl.go.jp/bib/8060097
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8060097
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• 抄録ライセンスフラグ: 使用不可