Decomposition of Monochlorobiphenyl by Grinding with Rare Earth Oxides

• Tanaka Yasumitsu

  RMC, MSNC, Sony Sendai Technology Center, Sony Corp.

• Zhang Qiwu

  IMRAM, Tohoku University

• Saito Fumio

  IMRAM, Tohoku University

抄録

Co-grinding of monochlorobiphenyl (BP-Cl) with rare earth oxides has been conducted and the mechanochemical decomposition of BP-Cl on the oxides has been investigated by a suite of analytical methods including X-ray diffraction (XRD), thermogravimetry (TG), Raman spectroscopy, electron spin resonance (ESR), gas chromatography/mass spectrometry (GC/MS). The experimental results have been compared with the use of CaO as additive and the differences have been discussed. It has been found that the use of rare earth oxides allows an efficient decomposition of BP-Cl and the time required to complete the decomposition reaction is much shorter than that by the use of CaO.

収録刊行物

• JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

  JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 39 (4), 469-474, 2006

  公益社団法人 化学工学会

キーワード

• Mechanochemical
• Dechlorination
• Rare Earth Oxides

詳細情報

• CRID: 1390001204569165312
• NII論文ID: 10018112644
• NII書誌ID: AA00709658
• DOI: 10.1252/jcej.39.469
• COI: 1:CAS:528:DC%2BD28XltVarsbg%3D
• ISSN: 18811299
• ISSN: 00219592
• NDL書誌ID: 7884377
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I7884377
• Web Site: http://www.jstage.jst.go.jp/article/jcej/39/4/39_4_469/_pdf
• 本文言語コード: en
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