Marked Difference in the Reaction Rate of an Azobenzene-based Photochromic Amorphous Molecular Material between Films Prepared by Vacuum Deposition and Spin Coating

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  • Takahiro Tanino
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Hideyuki Nakano
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Yasuhiko Shirota
    Department of Applied Chemistry, Faculty of Engineering, Osaka University

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<jats:title>Abstract</jats:title> <jats:p>A marked difference in the reaction rate of an azobenzene-based photochromic amorphous molecular material between films prepared by vacuum deposition and spin coating was found, the rate for the vacuum-deposited film being significantly faster compared to spin-coated amorphous film; this result indicates that the microstructures of amorphous films prepared by the above two methods are different from each other, suggesting that the local free volume of the vacuum-deposited film is smaller than that of the spin-coated film.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 35 (10), 1160-1161, 2006-09-16

    Oxford University Press (OUP)

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