Current status and future prospects of semiconducting alkaline-earth-metal silicides

  • SUEMASU Takashi
    Institute of Applied Physics, University of Tsukuba PRESTO, Japan Science and Technology Agency
  • IMAI Yoji
    National Institute of Advanced Industrial Science and Technology

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Other Title
  • 多元系シリサイドの新展開
  • 最近の展望 多元系シリサイドの新展開--半導体BaSi2を例に
  • サイキン ノ テンボウ タゲンケイ シリサイド ノ シンテンカイ ハンドウタイ BaSi2 オ レイ ニ
  • —半導体BaSi2を例に—

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Abstract

<p>β-FeSi2 has been extensively studied as a Si-based infrared-light emitter over the past ten years. On the other hand, alkaline-earth-metal silicides such as Mg2Si and BaSi2 have attracted less attention. However, they have very interesting features as follows. The band gap of Mg2Si can be controlled from 0.7 to 0 eV by replacing the Si atoms with other group 14 elements such as Ge, Sn and Pb. BaSi2 has a very large optical absorption coefficient, comparable to that of chalcopyrite semiconductors. In addition, it was recently reported that the band gap of BaSi2 increases from 1.3 eV by the replacement of some of the Ba atoms with Sr. In this article, recent studies on BaSi2 such as epitaxial growth techniques, electrical and optical properties and band structure calculations are described.</p>

Journal

  • Oyo Buturi

    Oyo Buturi 76 (3), 264-268, 2007-03-10

    The Japan Society of Applied Physics

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