Zinc(II) and Copper(I)–Ferrocenedicarboxylate Polyhedron and Polygon

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  • Young S Kim
    Department of Chemistry Education, Seoul National University
  • Jaheon Kim
    Department of Chemistry, Soongsil University
  • Don Kim
    Department of Chemistry, Pukyong National University
  • Hee K Chae
    Department of Chemistry Education, Seoul National University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Metal organometallic carboxylates with unusual polyhedral and rectangular shapes have been prepared by the reaction of 1,1′-ferrocenedicarboxylic acid (H2FDCA) with ZnII and CuII to give [Zn6O2(FDCA)5(H2O)(DMF)]·(DMF)4 (1), [Zn8O4(FDCA)6(H2O)3]·(DMA)4·(H2O)2 (2), and [Cu4(FDCA)2] (3), respectively (DMF = N,N′-dimethylformamide; DMA = N,N′-dimethylacetoamide). SQUID data of zinc compounds show that iron ions of the ferrocene moieties in the compounds exhibit antiferromagnetic coupling.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 36 (1), 150-151, 2006-12-16

    Oxford University Press (OUP)

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