Stereoselective C-Alkynylation, Allenylation, and Prop-2-ynylation Leading to Sugar Glycosides

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Author(s)

    • ISOBE Minoru
    • Laboratory of Organic Chemistry, Bioagricultural Sciences, Nagoya University

Abstract

Carbohydrates have been recognized and utilized for a long time as the starting materials for target-oriented syntheses toward optically active compounds. C-Glycosides are often employed for this purpose because they have much potential for the introduction of new stereogenic centers to the side chain. We describe herein various methods for the introduction of carbon chains to the sugar rings under acidic conditions, particularly in the form of alkynyl, allenyl, or prop-2-ynyl group at the anomeric position with high stereoselectivity.

Journal

  • Chemistry Letters

    Chemistry Letters 35(6), 552-557, 2006-06-05

    The Chemical Society of Japan

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Codes

  • NII Article ID (NAID)
    10019162120
  • NII NACSIS-CAT ID (NCID)
    AA00603318
  • Text Lang
    ENG
  • Article Type
    REV
  • ISSN
    03667022
  • Data Source
    CJP  J-STAGE 
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