Fabrication and Electrochemical Properties of High-density Graft Films with Ferrocene Moieties on ITO Substrates

• Sakakiyama Tomofumi

  Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University

• Ohkita Hideo

  Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University

• Ohoka Masataka

  Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University

• Ito Shinzaburo

  Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University

• Tsujii Yoshinobu

  Institute for Chemical Research, Kyoto University

• Fukuda Takeshi

  Institute for Chemical Research, Kyoto University

抄録

High-density graft films bearing ferrocene (Fc) moieties were fabricated on quartz and indium tin oxide (ITO) substrates by surface-initiated atom transfer radical polymerization (ATRP). The thickness of the film increased with the increase in the molecular weight of the polymer. We successfully observed quantitative electrochemical redox signals on the ITO substrates coated with a graft polymer. The cyclic voltammograms showed that all ferrocene moieties were electrochemically active.

収録刊行物

• Chemistry Letters

  Chemistry Letters 34 (10), 1366-1367, 2005

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390001204580824832
• NII論文ID: 10019351910
• NII論文ID: 130004423679
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2005.1366
• ISSN: 13480715
• ISSN: 03667022
• HANDLE: 2433/281586
• Web Site: https://academic.oup.com/chemlett/article-pdf/34/10/1366/55588909/cl.2005.1366.pdf
• 本文言語コード: en
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