Perfluorocarbon-based Liquid-Liquid Extraction for Separation of Transition Metal Ions

• MARUYAMA Tatsuo

  Department of Applied Chemistry, Graduate School of Engineering and Center for Future Chemistry, Kyushu University

• NAKASHIMA Kazunori

  Department of Applied Chemistry, Graduate School of Engineering and Center for Future Chemistry, Kyushu University

• KUBOTA Fukiko

  Department of Applied Chemistry, Graduate School of Engineering and Center for Future Chemistry, Kyushu University

• GOTO Masahiro

  Department of Applied Chemistry, Graduate School of Engineering and Center for Future Chemistry, Kyushu University

Abstract

We report a liquid-liquid extraction system based on perfluorocarbon (fluorous-solvent extraction) that allows selective extraction of metal ions from aqueous and organic phases to a perfluorocarbon phase (FC-72) with perfluorinated β-diketone (1,1,1,5,5,6,6,6-octafluoro-2,4-hexanedione), which can be followed by backward extraction using 1 M nitric acid.

Journal

• Analytical Sciences

  Analytical Sciences 23 (7), 763-765, 2007

  The Japan Society for Analytical Chemistry

Keywords

• Analytical Chemistry

Details

• CRID: 1390001204257632768
• NII Article ID: 130004441480
• NII Article ID: 10019525982
• NII Book ID: AA10500785
• DOI: 10.2116/analsci.23.763
• COI: 1:STN:280:DC%2BD2svgslWjtg%3D%3D
• ISSN: 13482246
• ISSN: 09106340
• NDL BIB ID: 8797838
• PubMed: 17625313
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8797838
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.23.763.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.23.763/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/23/7/23_7_763/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
• Abstract License Flag: Disallowed