Aggregating Structure of Hydrogen-Bonded Poly(4-vinylphenol)-N,N-Dimethyloctadecylamine Complex in Selective Solvent

• MASUNAGA Hiroyasu

  Japan Synchrotron Radiation Research Institute/SPring-8

• AKIBA Isamu

  The University of Kitakyushu

Bibliographic Information

Other Title

• ポリ（４‐ビニルフェノール）‐Ｎ，Ｎ‐ジメチルオクタデシルアミン複合体の選択溶媒中での会合構造
• ポリ(4-ビニルフェノール)-N,N-ジメチルオクタデシルアミン複合体の選択溶媒中での会合構造
• ポリ 4 ビニルフェノール N N ジメチルオクタデシルアミン フクゴウタイ ノ センタク ヨウバイチュウ デノ カイゴウ コウゾウ

Abstract

The aggregating structure of hydrogen-bonded comb-like poly(4-vinylphenol)-N,N-dimethyl-n-octadecylamine (PVPh-NDOA) complex in anisole, which is a selective solvent for NDOA, was investigated by small-angle X-ray scattering (SAXS). SAXS results showed that PVPh-NDOA complex formed rod-like aggregates in anisole at room temperature. The rod-like structure changed to spherical shape as the temperature was increased. Such a change in aggregating structure was related to formation-dissociation of hydrogen bonding between PVPh and NDOA.<br>

Journal

• KOBUNSHI RONBUNSHU

  KOBUNSHI RONBUNSHU 64 (7), 471-473, 2007

  The Society of Polymer Science, Japan

Keywords

• Poly(4-vinylphenol)
• Comb-Like Complex
• Hydrogen-Bond
• Small-Angle X-Ray Scattering

Details

• CRID: 1390001206521548672
• NII Article ID: 10019555772
• NII Book ID: AN00085011
• DOI: 10.1295/koron.64.471
• ISSN: 18815685
• ISSN: 03862186
• NDL BIB ID: 8904913
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8904913
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed