Rapid Coprecipitation Technique Using Yttrium Hydroxide for the Preconcentration and Separation of Trace Elements in Saline Water Prior to Their ICP-AES Determination

  • KAGAYA Shigehiro
    Graduate School of Science and Engineering for Research, University of Toyama
  • MIWA Satoshi
    Graduate School of Science and Engineering for Research, University of Toyama
  • MIZUNO Toshiyuki
    Graduate School of Science and Engineering for Research, University of Toyama
  • TOHDA Koji
    Graduate School of Science and Engineering for Research, University of Toyama

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抄録

Yttrium hydroxide quantitatively coprecipitated Be(II), Ti(IV), Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Pb(II) at pH 9.6 - 10.0 for seawater and pH 10.5 - 11.4 for a table-salt solution. The coprecipitated elements could be determined by inductively coupled plasma atomic emission spectrometry; yttrium was used as an internal standard element. The detection limits ranged from 0.0016 µg (Mn(II)) to 0.22 µg (Zn(II)) in 100 mL of sample solutions. The operation time required to separate 11 elements was approximately 30 min.

収録刊行物

  • Analytical Sciences

    Analytical Sciences 23 (8), 1021-1024, 2007

    社団法人 日本分析化学会

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