Synthesis of Highly Functionalized Alkenylphosphines by Lewis Acid-mediated Silylphosphination of Substituted Propiolates

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Author(s)

    • HAYASHI Minoru
    • Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University
    • MATSUURA Yutaka
    • Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University
    • KURIHARA Katsutoshi
    • Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University
    • MAEDA Daisuke
    • Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University
    • NISHIMURA Yasunobu
    • Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University
    • MORITA Emi
    • Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University
    • OKASAKA Miho
    • Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University
    • WATANABE Yutaka
    • Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University

Abstract

A synthesis of highly substituted alkenylphosphines by Lewis acid-mediated silylphosphination of substituted propiolates is described. The addition proceeded smoothly to give the corresponding acrylates, where the phosphino group attached at the β and the silyl group located at the α position of the resulting acrylate, in exclusively syn-stereochemistry.

Journal

  • Chemistry Letters

    Chemistry Letters 36(5), 634-635, 2007-05-05

    The Chemical Society of Japan

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Codes

  • NII Article ID (NAID)
    10019935920
  • NII NACSIS-CAT ID (NCID)
    AA00603318
  • Text Lang
    ENG
  • Article Type
    SHO
  • ISSN
    03667022
  • Data Source
    CJP  J-STAGE 
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