Fabrication of a Self-assembled Rotaxane Monolayer Consisting of a Viologen-functionalized Alkanethiol and α-Cyclodextrin Using Potential Sweep Method

Hiroto Murakami, Hiroko Chifu, Takamasa Sagara

doi:10.1246/cl.2007.1218

Fabrication of a Self-assembled Rotaxane Monolayer Consisting of a Viologen-functionalized Alkanethiol and α-Cyclodextrin Using Potential Sweep Method

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Hiroto Murakami

Department of Materials Engineering and Molecular Science, Graduate School of Science and Technology, Nagasaki University
Hiroko Chifu

Department of Materials Engineering and Molecular Science, Graduate School of Science and Technology, Nagasaki University
Takamasa Sagara

Department of Applied Chemistry, Faculty of Engineering, Nagasaki University

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<jats:title>Abstract</jats:title> <jats:p>A self-assembled monolayer of a rotaxane (rotaxane-SAM) consisting of N-(3,5-dimethoxybenzyl)-N′-6-mercaptohexylbipyridinium dibromide and α-cyclodextrin (α-CD) was successfully prepared using a potential sweep method by which unfavorable adsorption of α-CD and viologen dimer can be controlled.</jats:p>