Transition-metal-catalyzed Synthesis of Organophosphorous and Organosulfur Compounds

• Arisawa Mieko

  Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku Univertsity

• Yamaguchi Masahiko

  東北大学原子分子材料科学高等研究機構

Bibliographic Information

Other Title

• 有機リンおよびイオウ化合物の遷移金属触媒合成
• ユウキ リン オヨビ イオウ カゴウブツ ノ センイ キンゾク ショクバイ ゴウセイ

Abstract

Organoheteroatom compounds of phosphorous and sulfur are important in relation to the development of biologically active substances and materials. Conventional synthesis in general employed substitution reactions of organohalogen compounds with heteroatom reagents. It was considered that i) the addition reaction to unsaturated compounds; ii) the substitution reaction of C-H bond; iii) single bond metathesis would be more favorable, since the starting materials are readily available, and the reactions are atom-economical. Described here is the use of transition metal catalysis for such syntheses of organosulfur and organophosphorous compounds.

Journal

• Journal of Synthetic Organic Chemistry, Japan

  Journal of Synthetic Organic Chemistry, Japan 65 (12), 1213-1224, 2007

  The Society of Synthetic Organic Chemistry, Japan

Keywords

• rhodium
• palladium
• S-S bond cleavage
• addition
• C-H activation
• organophosphorous
• organosulfur

Details

• CRID: 1390001205311758592
• NII Article ID: 10020007202
• NII Book ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.65.1213
• COI: 1:CAS:528:DC%2BD2sXhsVCku7bF
• ISSN: 18836526
• ISSN: 00379980
• ISSN: http://id.crossref.org/issn/00379980
• NDL BIB ID: 9304102
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9304102
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed