Intermolecular Proton Transfer from Formaldehyde Intermediate to Anisole in Noncatalytic Pyrolysis : Phenol Produced without Hydrolysis

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Author(s)

Abstract

New reaction mechanism has been found for the pyrolysis of anisole according to the total product analysis based on the liquid- and gas-phase <SUP>1</SUP>H and <SUP>13</SUP>C NMR spectroscopy. Formaldehyde and benzene are produced in the first rate-determining step by the intramolecular proton transfer, and phenol, methane, and carbon monoxide in equal amounts successively through the fast intermolecular proton and hydride transfers from hot formaldehyde to anisole.

Journal

  • Chemistry Letters

    Chemistry Letters 35(12), 1334-1335, 2006-12-05

    The Chemical Society of Japan

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Codes

  • NII Article ID (NAID)
    10020134281
  • NII NACSIS-CAT ID (NCID)
    AA00603318
  • Text Lang
    ENG
  • Article Type
    SHO
  • ISSN
    03667022
  • Data Source
    CJP  J-STAGE 
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