Acetyl chloride-mediated synthesis of trans-2-〔(Diethoxyphosphorylamino)alkyl〕-4-aryl-5,5-dimethyl-1,3,2λ[5]-dioxaphosphorinane-2-oxide

• Zhiwei Miao

• Jianfeng Zhang

• Zhanwei Cui

書誌事項

タイトル別名

• Acetyl chloride mediated synthesis of trans 2 Diethoxyphosphorylamino alkyl 4 aryl 5 5 dimethyl 1 3 2 l 5 dioxaphosphorinane 2 oxide

抄録

N-Phosphoramino-protected six-membered cyclic α-aminophosphonates trans-2-[(diethoxyphosphorylamino)alkyl]-4-aryl-5,5-dimethyl-1,3,2λ5-dioxaphosphorinane-2-oxide 4a–4l were synthesized with the help of acetyl chloride. 31P NMR was used to trace the reaction process. A possible reaction mechanism was proposed and the stereochemistry of the title compounds was studied. In order to confirm the structure of 4, products 4f and 4k were recrystallized and determined by X-ray diffraction analysis.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 81 (5), 630-635, 2008

  Tokyo : Chemical Society of Japan

キーワード

• General Chemistry

詳細情報

• CRID: 1521417755501321984
• NII論文ID: 10021075624
• NII書誌ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.81.630
• NDL書誌ID: 9489837
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9489837
• Web Site: https://academic.oup.com/bcsj/article-pdf/81/5/630/56270135/bcsj.81.630.pdf
• 本文言語コード: en
• NDL 雑誌分類:
  • ZP1(科学技術--化学・化学工業)
• データソース種別:
  • NDL
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