Hydrogen adsorption properties of lantern-type dinuclear M(BDC)(DABCO)1/2

• Tohru Takei

• Jiro Kawashima

• Takato Ii

書誌事項

タイトル別名

• Hydrogen adsorption properties of lantern type dinuclear M BDC DABCO 1 2

抄録

The hydrogen adsorption properties and uptake capacities of three-dimensional microporous materials of lantern-type dinuclear M(BDC)(DABCO)1⁄2 (M=CoII, CuII, and ZnII; BDC = 1,4-benzenedicarboxylate, DABCO = 1,4-diazabicyclo[2.2.2]octane; Co(BDC)(DABCO)1⁄2 (1), Cu(BDC)(DABCO)1⁄2 (2), Zn(BDC)(DABCO)1⁄2 (3)) were investigated at various temperatures of 77–333 K and pressures up to 10 MPa using a PCT automatic measuring system (Sievert-type apparatus). The results indicated that uptake to 4.11, 2.70, and 3.17 wt % of hydrogen can be stored on 1, 2, and 3, respectively, at 77 K. The amounts of hydrogen are adsorbed by all complexes at around room temperature (293 K) and high-pressures are much lower (<0.5 wt %). Adsorption isotherms at around room temperature show a linear uptake relationship; all of them follow the Henry’s law. By measuring nitrogen gas adsorption/desorption, all complexes exhibit approximately Type-I isotherms according to the IUPAC classification and possess BET surface areas in the range of 1165 (for 3) to 1595 m2 g−1 (for 1). Further, the thermal stability of all complexes is high, in the range of about 500 K (for 3) to 600 K (for 1). These complexes were synthesized and characterized by X-ray powder diffraction pattern, TG/DTA, FT-IR, surface area analysis, and hydrogen adsorption measurements.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 81 (7), 847-856, 2008

  Tokyo : Chemical Society of Japan

キーワード

• General Chemistry

詳細情報

• CRID: 1520291855003849344
• NII論文ID: 10021076789
• NII書誌ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.81.847
• NDL書誌ID: 9573883
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9573883
• Web Site: https://academic.oup.com/bcsj/article-pdf/81/7/847/56270241/bcsj.81.847.pdf
• 本文言語コード: en
• NDL 雑誌分類:
  • ZP1(科学技術--化学・化学工業)
• データソース種別:
  • NDL
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