Synthesis and Photolysis of Biphenylenetetracarboxylic Dianhydride in Low-temperature Neon Matrixes

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  • Tadatake Sato
    Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)
  • Aiko Narazaki
    Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)
  • Yoshizo Kawaguchi
    Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)
  • Hiroyuki Niino
    Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)

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<jats:title>Abstract</jats:title> <jats:p>Biphenylenetetracarboxylic dianhydride was synthesized by dimerization of benzynedicarboxylic anhydride generated quantitatively by laser photolysis in low-temperature matrixes. Synthesized dianhydride was used as a precursor of matrix photolysis. It was isolated in a neon matrix and photolyzed to form biphenylynedicarboxylic anhydride, a novel aryne species.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 37 (3), 334-335, 2008-02-16

    Oxford University Press (OUP)

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