A Two-step and Hysteretic Spin-crossover Transition in New Cyano-bridged Hetero-metal FeIIAuI 2-Dimensional Assemblage
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- Takashi Kosone
- Department of Chemistry, Faculty of Science, Toho University
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- Chihiro Kachi-Terajima
- Department of Chemistry, Faculty of Science, Toho University
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- Chikahide Kanadani
- Department of Physics, Faculty of Science, Toho University
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- Toshiaki Saito
- Department of Physics, Faculty of Science, Toho University
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- Takafumi Kitazawa
- Department of Chemistry, Faculty of Science, Toho University
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<jats:title>Abstract</jats:title> <jats:p>A new hetero-metal 2-dimensional (2D) spin-crossover complex, {[FeII(3-Fpy)2][AuI(CN)2]2}n (3-Fpy = 3-fluoropyridine) has been synthesized and characterized crystallographically and magnetically. The complex consists of an octahedral FeII ion and a mononuclear [AuI(CN)2]− unit with a linear coordination geometry which combine to form an infinite 2D structure. The spin transition observed for this complex is accompanied by a drastic and reversible change of color from blue to purple.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 37 (4), 422-423, 2008-03-08
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360846644041273216
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- NII論文ID
- 10021079487
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- NII書誌ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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