Self-assembly-directed Spin Conversion of Iron(II) 1,2,4-Triazole Complexes in Solution and Their Effect on Photorelaxation Processes of Fluorescent Counter Ions

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  • Hiroyuki Matsukizono
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Keita Kuroiwa
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Nobuo Kimizuka
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Lipophilic, linear iron(II) 1,2,4-triazole complexes with 9,10-dimethoxyanthracene-2-sulfonate and 1-pyrenesulfonate counter ions are newly developed. These complexes are dispersed in toluene as nanofibers and display dynamic spin conversion characteristics. Photorelaxation process of 1-pyrenesulfonate accumulated on the complex is regulated depending on the spin state of iron(II) triazole complexes.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 37 (4), 446-447, 2008-03-15

    Oxford University Press (OUP)

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