Alcohol Oxidation in Ionic Liquid with UHP and Recyclable Amberlite IR-120 Acidic Resin: A Green Approach

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  • Nishi Bhati
    Synthetic Organic Chemistry Division, North-East Institute of Science and Technology
  • Kuladip Sarma
    Synthetic Organic Chemistry Division, North-East Institute of Science and Technology
  • Amrit Goswami
    Synthetic Organic Chemistry Division, North-East Institute of Science and Technology

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<jats:title>Abstract</jats:title> <jats:p>Amberlite IR-120 acidic resin, an age old polymer matrix, plays a significant role as catalyst in the oxidation of aromatic alcohols with urea–hydrogen peroxide in ionic liquid at 70 °C to disproportionate into phenols and carbonyl compounds in 30–60 min following two pathways. Under similar condition tertiary aromatic alcohol gave exclusively monohydroxyphenol accompanied by acetone. However, aliphatic and alicyclic alcohols yielded carbonyl compounds in moderate to good yields in 1–5 h.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 37 (5), 496-497, 2008-03-29

    Oxford University Press (OUP)

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