UV-Spectroscopic Quantitative Determination of Non-aromatic Amines in Ionic Liquids

• STARK Annegret

  Friedrich-Schiller University Jena, Institute for Technical Chemistry and Environmental Chemistry

• BRAUN Oliver

  Friedrich-Schiller University Jena, Institute for Technical Chemistry and Environmental Chemistry

• ONDRUSCHKA Bernd

  Friedrich-Schiller University Jena, Institute for Technical Chemistry and Environmental Chemistry

Abstract

In the last decade, ionic liquids have shown great promise in a plethora of applications. Nevertheless, little attention has been paid to the characterization of the purity of these fluids, which ultimately lead to non-reproducible data in the literature. Derivatization with carbon disulfide is used to quantitatively determine primary and secondary non-aromatic amines (detection limit: 0.2 wt%), such as 1-butylamine, morpholine or pyrrolidine, in ionic liquids. The corresponding dithiocarbamates formed are analyzed by ultraviolet spectroscopy at wavelengths between 277 and 285 nm.

Journal

• Analytical Sciences

  Analytical Sciences 24 (5), 681-683, 2008

  The Japan Society for Analytical Chemistry

Keywords

• Analytical Chemistry

Details

• CRID: 1390001204256697472
• NII Article ID: 130004441664
• NII Article ID: 10021100375
• NII Book ID: AA10500785
• DOI: 10.2116/analsci.24.681
• ISSN: 13482246
• ISSN: 09106340
• NDL BIB ID: 9483154
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9483154
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.24.681.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.24.681/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/24/5/24_5_681/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed