Application of Lead-Free Vanadium Sealing Glasses to the Flat Fluorescence Lump

  • Kouhara Yoshihiro
    Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Kagoshima University
  • Yoshida Masashiro
    Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Kagoshima University
  • Takei Takayuki
    Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Kagoshima University
  • Iwasaki Hiroshi
    Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Kagoshima University
  • Takemiya Tetsushi
    Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Kagoshima University
  • Hatate Yasuo
    Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Kagoshima University
  • Tsutsui Toshio
    Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Kagoshima University
  • Mizuta Kei
    Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Kagoshima University

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Other Title
  • 封着加工用バナジウム系鉛フリーガラスの平面蛍光管への応用と特性評価
  • フウチャク カコウヨウ バナジウムケイ ナマリ フリーガラス ノ ヘイメン ケイコウカン エ ノ オウヨウ ト トクセイ ヒョウカ

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Abstract

Lead-free glasses with a low melting temperature (lower than 600°C) and good chemical durability are desirable for the sealing process in the ceramic and electronic industries. In our previous studies, the quaternary systems (41.8 mol% V2O5–3.1 mol% ZnO–17.6 mol% BaO–37.5 mol% TeO2 or 53.0 mol% V2O5–4.0 mol% ZnO–22.4 mol% BaO–20.6 mol% P2O5) were confirmed to have excellent sealing and thermal properties. In this study, we carried out a thermal-shock test, a pressure-resistance test, and a continuous lighting test for evaluating the practical application. These lead-free glasses exhibited excellent performance and properties as a substitute for the commercial lead sealing glass.

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