有機合成化学と高分子科学  ラダー型π電子系の典型元素修飾

書誌事項

タイトル別名
  • Ladder π-Electron Materials with Main Group Elements
  • ラダーガタ パイ デンシケイ ノ テンケイ ゲンソ シュウショク

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抄録

The progress in organic electronics highly relies on the development of new excellent π-conjugated materials. ln this regard, ladder-type π-conjugated frameworks are promising building units, wherein the enhanced π-conjugation by their rigid coplanar structures leads to a set of desirable properties such as intense fluorescence and high carrier mobility. An effective modulation of this class of materials is to incorporate group 13-16 elements, such as B, Si, P, S, and Se, into the ladder frameworks. Exploitation of the features of these elements, unique orbital interaction, varied coordination/valence numbers, and structural features, allows us to create new fascinating molecular systems. Recent progresses in this direction are summarized, in particular, focusing on the chemistry of ladder oligo(p-phenylenevinylene)s and fused oligothiophenes.

収録刊行物

  • 高分子

    高分子 57 (3), 150-153, 2008

    公益社団法人 高分子学会

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