Characterization of Dissolved Organic Matter (DOM) in Lake Kasumigaura and Several DOM Sources Using Method of Three-Dimensional Excitation-Emission Matrix Fluorescence Spectra
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- KOMATSU Kazuhiro
- National Institute for Environmental Studies
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- IMAI Akio
- National Institute for Environmental Studies
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- MATSUSHIGE Kazuo
- National Institute for Environmental Studies
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- NARA Fumiko
- National Institute for Environmental Studies
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- KAWASAKI Nobuyuki
- National Institute for Environmental Studies
Bibliographic Information
- Other Title
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- 三次元励起蛍光スペクトル法による霞ケ浦湖水及び流域水中DOMの特性評価
- 3ジゲン レイキ ケイコウ スペクトルホウ ニ ヨル カスミガウラ コスイ オヨビ リュウイキスイチュウ DOM ノ トクセイ ヒョウカ
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Abstract
Three-dimensional excitation-emission matrix (EEM) fluorescence spectra were used to evaluate and compare the characteristics of dissolved organic matter (DOM) in lake and river waters as well as effluent from several sewage treatment plants. Our comparisons of the EEMs indicated a substantial difference in the peak profiles among the samples. For example, five peaks (i.e. Ex/Em = 225/280, Ex/Em = 225/340, Ex/Em = 240/420, Ex/Em = 340/430, and Ex/Em = 480/520nm) were observed on the EEM of the sewage treatment plant effluent, but only two peaks (i.e. Ex/Em = 240/420 and Ex/Em = 340/430nm) were observed in the case of the lake and river waters. Furthermore, one of the peaks (i.e. Ex/Em = 340/430), which has been used as an indicator of the humic-like groups of DOM, was actually found in the EEMs of both humic and non-humic fractions prepared by the XAD-8 resin fractionation method. The non-humic fraction consistently accounted for 30-50% of the peak intensity of the DOM . This result suggests that the peak at Ex/Em = 340/430 is not appropriate as an indicator of humic-like groups in DOM.
Journal
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- Journal of Japan Society on Water Environment
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Journal of Japan Society on Water Environment 31 (5), 261-267, 2008
Japan Society on Water Environment
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Details 詳細情報について
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- CRID
- 1390282680059089792
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- NII Article ID
- 10021158622
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- NII Book ID
- AN10372439
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- COI
- 1:CAS:528:DC%2BD1cXmvFaitbw%3D
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- ISSN
- 18813690
- 09168958
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- NDL BIB ID
- 9506705
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed