Hydrogen Absorption into Anodized Niobium Electrodes during Cathodic Polarization
-
- NAGAHARA Kazuhiro
- Graduate School of Engineering, Hokkaido University
-
- KIKUCHI Tatsuya
- Graduate School of Engineering, Hokkaido University
-
- FUSHIMI Kouji
- Graduate School of Engineering, Hokkaido University
-
- SAKAIRI Masatoshi
- Graduate School of Engineering, Hokkaido University
-
- TAKAHASHI Hideaki
- Graduate School of Engineering, Hokkaido University
-
- IZUMI Tomoo
- Cabot Supermetals K. K.
Bibliographic Information
- Other Title
-
- カソード分極中におけるアノード酸化皮膜化成ニオブ電極への水素吸収
- カソード ブンキョクチュウ ニ オケル アノード サンカ ヒマク カセイ ニオブ デンキョク エノ スイソ キュウシュウ
Search this article
Abstract
Cathodic polarization of niobium specimens that have been anodized galvanostatically up to Ea=100V, and then potentiostatically at Ea=100V has been investigated in a neutral borate solution. During potetiostatic cathodic polarization below Ec=−2.36V (vs. RHE) in both aerated and deaerated solutions, the cathodic current increased rapidly initially, and then increased gradually until it reached a steady value. Hydrogen gas evolution was observed during cathodic polarization below Ec=−2.36V with no formation of blisters and pits, suggesting that H+ reduction occurs mainly at the film surface. GD-OES spectra revealed that hydrogen species are enriched in the niobium substrate near the interface between anodic oxide films and the substrate at potentials below Ec=−2.36V, and that the trend is pronounced at lower potentials. Chemical shift was observed on Nb 3d and O 1s peaks in XPS spectra for the specimen at Ec=−3.36V, suggesting the formation of Nb2O3(OH)2.<br>Mechanism for the reaction during cathodic polarization in a neutral solution is discussed in terms of the proton reduction at the interfaces both between oxide films / solutions and between oxide films / substrates.
Journal
-
- Journal of The Surface Finishing Society of Japan
-
Journal of The Surface Finishing Society of Japan 59 (5), 326-332, 2008
The Surface Finishing Society of Japan
- Tweet
Details 詳細情報について
-
- CRID
- 1390001204116807168
-
- NII Article ID
- 10021169924
-
- NII Book ID
- AN1005202X
-
- ISSN
- 18843409
- 09151869
-
- NDL BIB ID
- 9503239
-
- Text Lang
- ja
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
-
- Abstract License Flag
- Disallowed