遷移金属触媒によるπ共役系高分子の構造制御合成  [in Japanese] Structure-Controlled Synthesis of π-Conjugated Polymers by Means of Transition-Metal Catalysts  [in Japanese]

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Author(s)

    • 脇岡 正幸 WAKIOKA Masayuki
    • 京都大学化学研究所 International Research Center for Elements Science, Institute for Chemical Research, Kyoto University
    • 滝田 良 TAKITA Ryo
    • 京都大学化学研究所 International Research Center for Elements Science, Institute for Chemical Research, Kyoto University
    • 小澤 文幸 OZAWA Fumiyuki
    • 京都大学化学研究所 International Research Center for Elements Science, Institute for Chemical Research, Kyoto University

Abstract

Recent progress in structure-controlled synthesis of π-conjugated polymers is described. A particular interest is focused on transition-metal-catalyzed polymerization that enables precise control of molecular weights and stereoregularity of polymers. The topics include: (a) chain-growth polycondensation to afford polythiophene, polyphenylene, and polyfluorene; (b) living ring-opening metathesis polymerization to give poly (phenylenevinylene); (c) polyaddition reactions based on stereoselective hydrosilylation and dimerization of alkynes; (d) stereocontrolled synthesis of poly (arylenevinylene)s (PAVs). The unique photochemical properties of PAVs are described.

Journal

  • NIPPON GOMU KYOKAISHI

    NIPPON GOMU KYOKAISHI 81(10), 431-437, 2008-10-15

    THE SOCIRETY OF RUBBER SCIENCE AND TECHNOLOGYY, JAPAN

References:  49

Codes

  • NII Article ID (NAID)
    10021873854
  • NII NACSIS-CAT ID (NCID)
    AN00189720
  • Text Lang
    JPN
  • Article Type
    REV
  • ISSN
    0029022X
  • NDL Article ID
    9681838
  • NDL Source Classification
    ZP17(科学技術--化学・化学工業--高分子化学・高分子化学工業--ゴム・プラスチックス)
  • NDL Call No.
    Z17-125
  • Data Source
    CJP  NDL  J-STAGE 
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