Structure-Controlled Synthesis of .PI.-Conjugated Polymers by Means of Transition-Metal Catalysts

• WAKIOKA Masayuki

  International Research Center for Elements Science, Institute for Chemical Research, Kyoto University

• TAKITA Ryo

  International Research Center for Elements Science, Institute for Chemical Research, Kyoto University

• OZAWA Fumiyuki

  International Research Center for Elements Science, Institute for Chemical Research, Kyoto University

Bibliographic Information

Other Title

• 遷移金属触媒がもたらす高性能，高機能，新規ポリマー　　遷移金属触媒によるπ共役系高分子の構造制御合成
• センイ キンゾク ショクバイ ニ ヨル パイ キョウヤクケイ コウブンシ ノ コウゾウ セイギョ ゴウセイ

Abstract

Recent progress in structure-controlled synthesis of π-conjugated polymers is described. A particular interest is focused on transition-metal-catalyzed polymerization that enables precise control of molecular weights and stereoregularity of polymers. The topics include: (a) chain-growth polycondensation to afford polythiophene, polyphenylene, and polyfluorene; (b) living ring-opening metathesis polymerization to give poly (phenylenevinylene); (c) polyaddition reactions based on stereoselective hydrosilylation and dimerization of alkynes; (d) stereocontrolled synthesis of poly (arylenevinylene)s (PAVs). The unique photochemical properties of PAVs are described.

Journal

• NIPPON GOMU KYOKAISHI

  NIPPON GOMU KYOKAISHI 81 (10), 431-437, 2008

  THE SOCIRETY OF RUBBER SCIENCE AND TECHNOLOGYY, JAPAN

Keywords

• π-Conjugated Polymer
• Precision Polymerization
• Molecular-Weight Control
• Stereocontrolled Synthesis

Details

• CRID: 1390282681539581056
• NII Article ID: 10021873854
• NII Book ID: AN00269207
• DOI: 10.2324/gomu.81.431
• ISSN: 18840442
• ISSN: 0029022X
• NDL BIB ID: 9681838
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9681838
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed