Development of Precision Polymers and Advanced Functional Polymers Starting from Substituted Acetylenes

  • SHIOTSUKI Masashi
    Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University Katsura Campus
  • SANDA Fumio
    Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University Katsura Campus
  • MASUDA Toshio
    Department of Environmental and Biotechnological Frontier Engineering, Faculty of Engineering, Fukui University of Technology

Bibliographic Information

Other Title
  • 遷移金属触媒がもたらす高性能,高機能,新規ポリマー  置換アセチレン等を出発モノマーとする精密重合高分子および先端機能高分子の開発
  • ソウセツ トクシュウ センイ キンゾク ショクバイ ガ モタラス コウセイノウ コウキノウ シンキ ポリマー チカン アセチレン トウ オ シュッパツ モノマー ト スル セイミツ ジュウゴウ コウブンシ オヨビ センタン キノウ コウブンシ ノ カイハツ

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Abstract

This article reviews the development of transition metal catalysts for substituted acetylenes. These catalysts enable us to synthesize a wide variety of substituted polyacetylenes, whose molecular weights and polydispersities can be controlled in some cases. Most of the polymers are soluble in common solvents and stable enough in the air unlike non-substituted polyacetylene. They exhibit interesting features and functions including helix formation, high gas permeability, and photoelectronic properties.

Journal

  • NIPPON GOMU KYOKAISHI

    NIPPON GOMU KYOKAISHI 81 (11), 473-480, 2008

    THE SOCIRETY OF RUBBER SCIENCE AND TECHNOLOGYY, JAPAN

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