Synthesis of an Organic-soluble π-Conjugated [1]Rotaxane

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  • Susumu Tsuda
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University
  • Jun Terao
    Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University
  • Nobuaki Kambe
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University

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<jats:title>Abstract</jats:title> <jats:p>An organic-soluble π-conjugated [1]rotaxane has been synthesized by intramolecular self-inclusion of a lipophilic permethylated α-cyclodextrin bearing a rigid π-conjugated system as a guest moiety. End-capping has been achieved successfully by connecting an aniline moiety without using bulky stoppers. The structure of the [1]rotaxane was determined by 2D NMR spectroscopy.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 38 (1), 76-77, 2008-12-13

    Oxford University Press (OUP)

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