Dispersion-Flocculation Behavior of Fine Lead Particles in an Organic Solvent
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- Tsunekawa Masami
- Graduate School of Engineering, Hokkaido University
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- Sasaki Yuta
- Graduate School of Engineering, Hokkaido University
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- Nakamura Yoshiaki
- Graduate School of Engineering, Hokkaido University
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- Ito Mayumi
- Graduate School of Engineering, Hokkaido University
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- Hiroyoshi Naoki
- Graduate School of Engineering, Hokkaido University
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- Yoo Kyoung Keun
- Korea Institute of Geoscience & Mineral Resources
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Methyl ethyl ketone (MEK) is a good solvent for polyvinyl chloride (PVC) and it has been proposed for use in PVC recycling. In the recycling process, fine particles of 3PbO·PbSO4·H2O, used as a thermal stabilizer in PVC products, are dispersed and not dissolved in the solvent. To establish methods for removing of 3PbO·PbSO4·H2O particles from the solvent, factors affecting the dispersion-flocculation behavior of the particles in MEK were investigated.<BR>The zeta potential and particle distribution of 3PbO·PbSO4·H2O particles in MEK solutions containing known amounts of H2O were measured. Above 5 vol%H2O in MEK solutions, the zeta potential of 3PbO·PbSO4·H2O particles approached zero and the flocculation of particles was achieved. In addition, it was found that Pb2+ and Cl− affect the zeta potential of the particles. These results indicate that the dispersion-flocculation behavior of lead particles can be influenced by the concentration of H2O, Pb2+, and Cl− in MEK.
収録刊行物
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- MATERIALS TRANSACTIONS
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MATERIALS TRANSACTIONS 49 (9), 2119-2123, 2008
公益社団法人 日本金属学会
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詳細情報 詳細情報について
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- CRID
- 1390282679225532288
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- NII論文ID
- 10024272286
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- NII書誌ID
- AA1151294X
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- COI
- 1:CAS:528:DC%2BD1cXhtlSrurbF
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- ISSN
- 13475320
- 13459678
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- NDL書誌ID
- 9629454
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 使用不可