三核ルテニウ厶クラスター上での炭化水素配位子の骨格転位

• 高尾 俊郎

• 鈴木 寛治

  東京工業大学大学院理工学研究科

書誌事項

タイトル別名

• Skeletal Rearrangement of a Hydrocarbyl Moiety on a Triruthenium Cluster
• 三核ルテニウムクラスター上での炭化水素配位子の骨格転位
• サンカク ルテニウムクラスター ジョウ デ ノ タンカスイソ ハイイシ ノ コッカク テンイ

抄録

The reactivity of transition metal cluster complexes has been of special interest in these days in the area of organometallic chemistry, owing to their capability of activating substrates through the cooperative effects of multiple metal centers. Unique reactivity of the transition metal clusters likely stems from their ability for multiple coordination of the substrate to the metal centers and the multi-electron transfer between the substrate and the cluster. Thus far, we have demonstrated numbers of examples of cooperative activation through extending the reaction chemistry of di- and triruthenium polyhydrido complexes, [(C₅Me₅)Ru]₂(μ-H)₄ and [(C₅Me₅)Ru]₃(μ-H)₂(μ₃-H)₂ (1). We report herein the remarkable shape-selectivity observed in the reactions of 1 with acyclic and cyclic 1,3-dienes and unusual skeletal rearrangements of trinuclear ruthenacyclic complexes including carbon-carbon bond scission/formation steps induced by the cooperative action of the adjacent metal centers.

収録刊行物

• 有機合成化学協会誌

  有機合成化学協会誌 67 (5), 475-485, 2009

  公益社団法人 有機合成化学協会

キーワード

• polyhydrido complexes
• ruthenium polyhydride
• polyhydrido cluster
• <i>nido</i>-ruthenacycle
• <i>closo</i>-ruthenacycle
• agostic interaction
• diene complex

詳細情報

• CRID: 1390001205313185664
• NII論文ID: 10024968707
• NII書誌ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.67.475
• COI: 1:CAS:528:DC%2BD1MXmtFKku7k%3D
• ISSN: 18836526
• ISSN: 00379980
• NDL書誌ID: 10306251
• Web Site: http://id.ndl.go.jp/bib/10306251
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I10306251
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• 抄録ライセンスフラグ: 使用不可