担持Re触媒を用いたベンゼンと酸素からのフェノールの直接合成反応  [in Japanese] Direct Phenol Synthesis from Benzene and Oxygen on Supported Rhenium Catalysts  [in Japanese]

Access this Article

Search this Article

Author(s)

Abstract

Phenol is one of the most important chemicals in industry and it is produced from cumene process from benzene. Direct phenol synthesis from benzene and O<sub>2</sub> is an alternative way to produce phenol efficiently. We have succeeded in preparing a HZSM-5-zeolite-supported Re catalyst, which was highly active and selective for direct phenol synthesis from benzene and O<sub>2</sub> (steady-state reaction: 5.8% benzene conversion and 88% phenol selectivity, pulse reaction: 9.9% benzene conversion and 94% phenol selectivity) in the presence of NH<sub>3</sub>. The formation of active Re clusters, their structural change, and the role of NH<sub>3</sub> which are relevant to the selective benzene oxidation were investigated.

Journal

  • Journal of Synthetic Organic Chemistry, Japan

    Journal of Synthetic Organic Chemistry, Japan 67(6), 643-650, 2009-06-01

    The Society of Synthetic Organic Chemistry, Japan

References:  24

  • <no title>

    CENTI G.

    Encyclopedia of Catalysis, Selective Oxidation

    Cited by (1)

  • <no title>

    GUBELMANN H.

    US Patent 5001280, 1988

    Cited by (1)

  • <no title>

    GUBELMANN H.

    EP Patent 0341165, 1988

    Cited by (1)

  • <no title>

    KHARITONOV A. S.

    Russian Patent 4445646, 1988

    Cited by (1)

  • <no title>

    SUZUKI E.

    Chem. Lett. 1988, 953

    Cited by (1)

  • <no title>

    PANOV G. I.

    Cattech 4, 18, 2000

    Cited by (1)

  • <no title>

    PIRUTKO L. V.

    Appl. Catal. A : General 227, 143, 2002

    Cited by (1)

  • <no title>

    PANOV G. I.

    J. Mol. Catal. 61, 85, 1990

    Cited by (1)

  • <no title>

    HENSEN E. J. M.

    J. Catal. 233, 136, 2005

    Cited by (1)

  • <no title>

    HENSEN E. J. M.

    J. Catal. 233, 123, 2005

    Cited by (1)

  • <no title>

    ZHU Q.

    J. Catal. 221, 575, 2002

    Cited by (1)

  • <no title>

    HENSEN E.

    J. Catal. 226, 466, 2004

    Cited by (1)

  • <no title>

    KUBACKA A.

    J. Catal. 250, 184, 2007

    Cited by (1)

  • <no title>

    HAGGIN J.

    Chem. Eng. News 1993, 23

    Cited by (1)

  • <no title>

    BAL R.

    Angew. Chem. Int. Ed. 45, 448, 2006

    Cited by (1)

  • <no title>

    TADA M.

    Catal. Today 117, 141, 2006

    Cited by (1)

  • <no title>

    TADA M.

    J. Phys. Chem. C 111, 10095, 2007

    Cited by (1)

  • <no title>

    IWASAWA Y. ed.

    Tailored Metal Cataysts, 1986

    Cited by (1)

  • <no title>

    IWASAWA Y.

    Acc. Chem. Res. 30, 103, 1997

    Cited by (1)

  • <no title>

    TADA M.

    Annu. Rev. Mater. Res. 35, 397, 2005

    Cited by (1)

  • <no title>

    TADA M.

    Chem. Commun. 2006, 2833

    Cited by (1)

  • <no title>

    TADA M.

    Handbook of Heterogeneous Catalysis 539, 2007

    Cited by (1)

  • <no title>

    NIWA S.

    Science 295, 105, 2002

    Cited by (11)

  • <no title>

    YAMANAKA H.

    J. Mol. Catal. A : Chem. 178, 89, 2002

    Cited by (7)

Codes

  • NII Article ID (NAID)
    10024969552
  • NII NACSIS-CAT ID (NCID)
    AN0024521X
  • Text Lang
    JPN
  • Article Type
    ART
  • ISSN
    00379980
  • NDL Article ID
    10334818
  • NDL Source Classification
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL Call No.
    Z17-256
  • Data Source
    CJP  NDL  J-STAGE 
Page Top