Recent Progress in Electrochemical Surface Science with Atomic and Molecular Levels

  • YE Shen
    Catalysis Research Center, Hokkaido University PRESTO, Japan Science and Technology Agency (JST)
  • KONDO Toshihiro
    Graduate School of Humanities and Sciences, Ochanomizu University
  • HOSHI Nagahiro
    Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University
  • INUKAI Junji
    Fuel Cell Natomaterials Center, University of Yamanashi
  • YOSHIMOTO Soichiro
    Priority Organization for Innovation and Excellence, Kumamoto University
  • OSAWA Masatoshi
    Catalysis Research Center, Hokkaido University
  • ITAYA Kingo
    WPI Advanced Institute for Material Research, Tohoku University Department of Applied Chemistry, Graduate School of Engineering, Tohoku University

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抄録

Until the mid 1980’s, there had been only few in situ methods available for structural determination of an electrode surface in solution at atomic and monolayer levels. Nowadays, many powerful in situ techniques, such as electrochemical scanning tunneling microscopy (EC-STM), infrared reflection absorption spectroscopy (IRAS), surface-enhanced Raman scattering (SERS), and surface-enhanced infrared reflection absorption spectroscopy (SEIRAS), second harmonic generation (SHG), sum frequency generation (SFG), and surface X-ray scattering (SXS) have been widely employed to characterize the electrode surfaces under potential control with atomic and/or molecular resolution. The object of this review is to highlight some of the progress on in situ methods at solid-liquid interface with atomic and molecular levels. Several selected topics are focused on, specifically adsorbed anions on metal surface, electrocatalysis of the carbon oxide oxidation and xygen reduction, and direct observation of single crystal electrode surfaces.

収録刊行物

  • Electrochemistry

    Electrochemistry 77 (4), E1-E1, 2009

    公益社団法人 電気化学会

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