Preparation of Iron-Containing Hectorite-Like Swelling Silicate
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- Ogawa Makoto
- Department of Earth Sciences and Graduate School of Science and Engineering, Waseda University
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- Matsutomo Takayuki
- Department of Earth Sciences and Graduate School of Science and Engineering, Waseda University
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- Okada Tomohiko
- Department of Chemistry and Material Engineering, Faculty of Engineering, Shinshu University
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Abstract
Iron-containing hectorite-like layered silicate was synthesized by the reaction of LiF, Mg(OH)2, colloidal silica, and FeCl3 in aqueous suspension at 100 °C for 2 days. From X-ray diffraction and infrared spectroscopic analysis, the formation of hectorite-like layered silicate was shown. Dimethyldioctadecylammonium and 1,1′-dimethyl-4,4′-bipyridinium (methyl viologen) ions were intercalated by cation-exchange reactions into the interlayer space of the iron-containing silicate. The intercalated amounts of both cationic species were larger compared to iron-free layered silicate, showing increase in the layer charge density of the silicate by the incorporation of iron(III). The increase in the layer charge was thought to be derived from isomorphous substitution of silicon(IV) by iron(III) in the silicate layer. The structural iron(III) was reduced to iron(II) by reaction with sodium dithionite, which was shown by a color-change (yellow to green) and the increase in the intercalated amounts of dimethyldioctadecylammonium and 1,1′-dimethyl-4,4′-bipyridinium ions.
Journal
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 82 (3), 408-412, 2009
The Chemical Society of Japan
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Details 詳細情報について
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- CRID
- 1390001204144050176
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- NII Article ID
- 10025116926
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- NII Book ID
- AA00580132
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- ISSN
- 13480634
- 00092673
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- NDL BIB ID
- 10178910
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed