Preparation of Poly(vinylidene fluoride-<i>co</i>-trifluoroethylene) Film with a Hydrophilic Surface by Direct Surface-initiated Atom Transfer Radical Polymerization without Pretreatment

• Taichi Kimura

  Graduate School of Engineering, Kyushu University

• Motoyasu Kobayashi

  Institute for Materials Chemistry and Engineering, Kyushu University

• Masamichi Morita

  Daikin Industries Ltd

• Atsushi Takahara

  Graduate School of Engineering, Kyushu University

抄録

Surface-initiated atom transfer radical polymerization (ATRP) of tert-butyl acrylate was carried out directly from a nonmodified poly(vinylidene fluoride-co-trifluoroethylene) [P(VDF-co-TrFE)] film surface to give a polymer brush, which was further converted to a poly(acrylic acid sodium salt) brush by hydrolysis. A hydrophilic surface was successfully created at the outermost surface of P(VDF-co-TrFE) film without any change in the bulk physical properties. Also the effect of surface nanotexture formation on wettability was investigated.

収録刊行物

• Chemistry Letters

  Chemistry Letters 38 (5), 446-447, 2009-04-04

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360565169064700032
• NII論文ID: 10025121837
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2009.446
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/38/5/446/56257103/cl.2009.446.pdf
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