Optical Sensor of Anionic Surfactants Using Solid-Phase Extraction with a Lactone-form Rhodamine B Membrane

• MASADOME Takashi

  Department of Applied Chemistry, Faculty of Engineering, Shibaura Institute of Technology

• AKATSU Motoo

  Department of Applied Chemistry, Faculty of Engineering, Shibaura Institute of Technology

Abstract

An optical sensor for the detection of anionic surfactants was developed. The optical sensing membrane is a 2-nitrophenyloctyl ether-plasticized poly(vinyl chloride) membrane incorporating a lactone-form Rhodamine B (L-RB). The response of the optical membrane to anionic surfactants was a result of the ion-pair coextraction of an anionic surfactant and a proton into the PVC membrane. The L-RB forms an ion associate with the extracted anionic surfactant; simultaneously, the formed L-RB ion associate is accompanied by a spectral change. Namely, the extracted anionic surfactant changes the color of the membrane from light pink to dark pink (absorption maximum; 558 nm). The optical membrane responds to anionic surfactants, such as dodecylbenzenesulfonate, dodecylsulfate and di-2-ethylhexyl sulfosuccinate in the concentration range from 1 to 50 µM.

Journal

• Analytical Sciences

  Analytical Sciences 24 (6), 809-812, 2008

  The Japan Society for Analytical Chemistry

Keywords

• Analytical Chemistry

Details

• CRID: 1390001204255998336
• NII Article ID: 10025204677
• NII Book ID: AA10500785
• DOI: 10.2116/analsci.24.809
• ISSN: 13482246
• ISSN: 09106340
• NDL BIB ID: 9522241
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9522241
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.24.809.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.24.809/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/24/6/24_6_809/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed